The history of tungsten, the strongest natural metal on earth
The History of Tungsten
With a tensile strength of 1,510 megapascals, we now know tungsten as the strongest naturally occurring metal on Earth.
Today’s infographic is from Almonty Industries, a tungsten producer, and it reveals the history of tungsten.
Interestingly, the infographic shows that despite tungsten’s strength, most of civilization has lived without any practical use of the metal. That’s because tungsten wasn’t officially discovered until the 18th century – though, as you will see, it was a thorn in the side of metallurgists for many centuries before that.
FROM THE HEAVENS
Like all elements with an atomic number higher than iron, tungsten cannot be created by nuclear fusion in stars like our sun.
Instead, tungsten is thought to be formed from the explosions of massive stars. Each supernova explosion has so much energy, that these newly created elements are jettisoned at incredible speeds of 30,000 km/s, or 10% of the speed of light – and that’s how they get dispersed throughout the universe.
Supernova explosions don’t happen often – as a result, in every 1,000,000 grams of the Earth’s crust, there are only 1.25 grams of tungsten.
AN UNUSUAL HISTORY
In the periodic table, tungsten is listed under the letter “W”. That’s because two names for the same metal actually arose simultaneously.
WOLFRAM: derived from the German words WOLF (English: wolf) and the Middle High German word RAM (English: dirt).
In the Middle Ages, tin miners in Germany complained about a mineral (wolframite) that accompanied tin ore and reduced tin yields when smelting.
With a longish, hair-like appearance, wolframite was thought to be a “wolf” that ate up the tin. Wolframite had plagued metallurgists for many centuries, until tungsten was discovered and proper methods were developed to deal with the heavy metal.
TUNGSTEN: derived from the Swedish words TUNG (English: heavy) and STEN (English: stone) due to its density
Scheelite, the other important tungsten ore, was discovered in an iron mine in Sweden in 1750.
It garnered interest for its incredible density – which is why it was named “heavy stone”.
The metal was discovered by Spanish nobleman Juan José D´Elhuyar, who eventually synthesized tungsten from both wolframite and scheelite – showing they were both minerals from the same new element.
HISTORY OF TUNGSTEN USES
Discoveries in tungsten use can be loosely linked to four fields: chemicals, steel and super alloys, filaments, and carbides.
1847: Tungsten salts are used to make colored cotton and to make clothes used for theatrical and other purposes fireproof.
1855: The Bessemer process is invented, allowing for the mass production of steel. At the same time, the first tungsten steels are being made in Austria.
1895: Thomas Edison investigated materials’ ability to fluoresce when exposed to X-rays, and found that calcium tungstate was the most effective substance.
1900: High Speed Steel, a special mix of steel and tungsten, is exhibited at the World Exhibition in Paris. It maintains its hardness at high temperatures, perfect for use in tools and machining.
1903: Filaments in lamps and lightbulbs were the first use of tungsten that made use of its extremely high melting point and its electrical conductivity. The only problem? Early attempts found tungsten to be too brittle for widespread use.
1909: William Coolidge and his team at General Electric the U.S. are successful in discovering a process that creates ductile tungsten filaments through suitable heat treatment and mechanical working.
1911: The Coolidge Process is commercialized, and in a short time tungsten light bulbs spread all over the world equipped with ductile tungsten wires.
1913: A shortage in industrial diamonds in Germany during WWII leads researchers to look for an alternative to diamond dies, which are used to draw wire.
1914: “It was the belief of some Allied military experts that in six months Germany would be exhausted of ammunition. The Allies soon discovered that Germany was increasing her manufacture of munitions and for a time had exceeded the output of the Allies. The change was in part due to her use of tungsten high-speed steel and tungsten cutting tools. To the bitter amazement of the British, the tungsten so used, it was later discovered, came largely from their Cornish Mines in Cornwall.” – From K.C. Li’s 1947 book “TUNGSTEN”
1923: A German electrical bulb company submits a patent for tungsten carbide, or hardmetal. It’s made by “cementing” very hard tungsten monocarbide (WC) grains in a binder matrix of tough cobalt metal by liquid phase sintering.
The result changed the history of tungsten: a material which combines high strength, toughness and high hardness. In fact, tungsten carbide is so hard, the only natural material that can scratch it is a diamond. (Carbide is the most important use for tungsten today.)
1930s: New applications arose for tungsten compounds in the oil industry for the hydrotreating of crude oils.
1940: The development of iron, nickel, and cobalt-based superalloys begin, to fill the need for a material that can withstand the incredible temperatures of jet engines.
1942: During World War II, the Germans were the first to use tungsten carbide core in high velocity armor piercing projectiles. British tanks virtually “melted” when hit by these tungsten carbide projectiles.
1945: Annual sales of incandescent lamps are 795 million per year in the U.S.
1950s: By this time, tungsten is being added into superalloys to improve their performance.
1960s: New catalysts were born containing tungsten compounds to treat exhaust gases in the oil industry.
1964: Improvements in efficiency and production of incandescent lamps reduce the cost of providing a given quantity of light by a factor of thirty, compared with the cost at introduction of Edison’s lighting system.
2000: At this point, about 20 billion meters of lamp wire are drawn each year, a length which corresponds to about 50 times the earth-moon distance. Lighting consumes 4% and 5% of the total tungsten production.
Today, tungsten carbide is extremely widespread, and its applications include metal cutting, machining of wood, plastics, composites, and soft ceramics, chipless forming (hot and cold), mining, construction, rock drilling, structural parts, wear parts and military components.
Tungsten steel alloys are also used the in the production of rocket engine nozzles, which must have good heat resistant properties. Super-alloys containing tungsten are used in turbine blades and wear-resistant parts and coatings.
However, at the same time, the reign of the incandescent lightbulb has come to an end after 132 years, as they start to get phased out in the U.S. and Canada.